Investigating fracture activation and CO2 migration in layered shale caprock: a phase-field approach

Authors

  • Yanji Fu College of Water Conservancy and Hydropower Engineering, Hohai University, Nanjing 210098, China
  • Shaobo Qiao College of Water Conservancy and Hydropower Engineering, Hohai University, Nanjing 210098, China
  • Huimin Wang College of Water Conservancy and Hydropower Engineering, Hohai University, Nanjing 210098, China
  • Jia Liu State Key Laboratory of Eco-hydraulics in Northwest Arid Region, Xi’an University of Technology, Xi’an 710048, China
  • Zhihan Li College of Water Conservancy and Hydropower Engineering, Hohai University, Nanjing 210098, China
  • Jinchang Sheng College of Water Conservancy and Hydropower Engineering, Hohai University, Nanjing 210098, China https://orcid.org/0000-0002-6892-1661

Abstract

Although low-permeability layered shale has been regarded as a natural barrier for CO2 leakage, the accumulation of CO2 beneath the caprock may reactivate original fractures and even connect interlayers. This behavior significantly threatens the sealing integrity of layered shale caprock. Therefore, our study defines the "weak interlayer" as thin layer with low mechanical strength. Subsequently, we developed a phase-field framework to investigate initial fracture activation, fracture extension and deflection, and pore pressure dispersion within layers. The accuracy of the proposed model was validated through tensile experiments on 2D notched plates and hydraulic fracturing experiments conducted on specimens containing circular perforations. Simulation results indicate that while the increase in in-situ stress raises the threshold for activating original fractures, their extension tends to be along the vertical direction. Similarly, a reduction in horizontal stress accelerates the fracture extension in the vertical direction. Lowering the permeability of "weak interlayer" hinders lateral dispersion of CO2 pressure, promoting vertical migration through the caprock. Conversely, reducing the injection rate allows easier lateral migration of CO2 along "weak interlayer", thereby improving sealing efficiency. These findings provide practical guidance for site selection in geological CO2 geological sequestration, insights into fracture activation, propagation, and connectivity, and an assessment of layered shale caprock sealing efficiency.

DOI:

https://doi.org/10.46690/gs.2026.01.03

Keywords:

Layered shale caprock, weak interlayers, phase field method, CO2 pressure, sealing efficiency

References

Bourdin B, Francfort G A, Marigo JJ. 2000. Numerical experiments in revisited brittle fracture. Journal of the Mechanics and Physics of Solids, 48:797–826. https://doi.org/10.1016/S0022-5096(99)00028-9.

Borden MJ, Verhoosel CV, Scott MA, et al. 2012. A phase field description of dynamic brittle fracture. Computer Methods in Applied Mechanics and Engineering, 217–220:77–95. https://doi.org/10.1016/j.cma.2012.01.008.

Chen B, Qi L, Tan Y, Liu W, Zhang Y. 2024. Caprock sealing integrity and key indicators of CO2 geological storage considering the effect of hydraulic-mechanical coupling: X field in the Bohai Bay Basin, China. Engineering Geology, 342:107741. https://doi.org/10.1016/j.enggeo.2024.107741.

Francfort G A, Marigo J-J. 1998. Revisiting brittle fracture as an energy minimization problem. Journal of the Mechanics and Physics of Solids, 46:1319–1342. https://doi.org/10.1016/S0022-5096(98)00034-9.

Kaldi J, Daniel R, Tenthorey E, et al. 2013. Containment of CO2 in CCS: Role of caprocks and faults. Energy Procedia, 37:5403–5410. https://doi.org/10.1016/j.egypro.2013.06.458.

Lee J, Min K-B, Rutqvist J. 2013. Ground heaving and leakage analysis for sequestration of CO2 in geological media considering fractures in caprock. Energy Procedia, 37:4504–4510. https://doi.org/10.1016/j.egypro.2013.06.356.

Lee S, Wheeler M F, Wick T. 2016. Pressure and fluiddriven fracture propagation in porous media using an adaptive finite element phase field model. Computer Methods in Applied Mechanics and Engineering, 305:111–132. https://doi.org/10.1016/j.cma.2016.02.037.

Li K, Zhou S. 2019. Numerical investigation of multizone hydraulic fracture propagation in porous media: New insights from a phase field method. Journal of Natural Gas Science and Engineering, 66:42–59. https://doi.org/10.1016/j.jngse.2019.03.018.

Liu J, Kai Y, Yi X, et al. 2019. Study on fracture behavior of bedded shale in three-point-bending test based on hybrid phase-field modelling. Theoretical and Applied Fracture Mechanics, 104:102382. https://doi.org/10.1016/j.tafmec.2019.102382.

Liu J, Liang X, Xue Y, et al. 2020. Investigation on crack initiation and propagation in hydraulic fracturing of bedded shale by hybrid phase-field modeling. Theoretical and Applied Fracture Mechanics, 108:102651. https://doi.org/10.1016/j.tafmec.2020.102651.

Liu J, Xue Y, Chen W, et al. 2021. Variational phase-field model based on lower-dimensional interfacial element in FEM framework for investigating fracture behavior in layered rocks. Engineering Fracture Mechanics, 255:107962. https://doi.org/10.1016/j.engfracmech.2021.107962.

Liu J, Xue Y, Zhang Y, et al. 2022. Phase-field modeling for dynamic cracking behavior in bedded shale. Theoretical and Applied Fracture Mechanics, 121:103480. https://doi.org/10.1016/j.tafmec.2022.103480.

Liu L, Zhu W, Wei C, et al. 2018. Microcrack-based geomechanical modeling of rock-gas interaction during supercritical CO2 fracturing. Journal of Petroleum Science and Engineering, 164:91–102. https://doi.org/10.1016/j.petrol.2018.01.049.

Mikelić A, Wheeler MF, Wick T. 2015. A phase-field method for propagating fluid-filled fractures coupled to a surrounding porous medium. SIAM Journal on Multiscale Modeling & Simulation, 13(1):367–398. https://doi.org/10.1137/140967118.

Mikelić A, Wheeler MF, Wick T. 2015. A quasistatic phase field approach to pressurized fractures. Nonlinearity, 28(5):1371–1399. https://doi.org/10.1088/0951-7715/28/5/1371.

Miehe C, Hofacker M, Welschinger F. 2010. A phase field model for rate-independent crack propagation: Robust algorithmic implementation based on operator splits. Computer Methods in Applied Mechanics and Engineering, 199:2765–2778. https://doi.org/10.1016/j.cma.2010.04.011.

Newell P, Martinez M J. 2020. Numerical assessment of fault impact on caprock seals during CO2 sequestration. International Journal of Greenhouse Gas Control, 94:102890. https://doi.org/10.1016/j.ijggc.2019.102890.

Onoja MU, Williams JDO, Vosper H, et al. 2019. Effect of sedimentary heterogeneities in the sealing formation on predictive analysis of geological CO2 storage. International Journal of Greenhouse Gas Control, 82:229–243. https://doi.org/10.1016/j.ijggc.2019.01.013.

Span R, Wagner W. 1996. A new equation of state for carbon dioxide covering the fluid region from the triple-point temperature to 1100 K at pressures up to 800 MPa. Journal of Physical and Chemical Reference Data, 25(6):1509–1596. https://doi.org/10.1063/1.555991.

Rutqvist J, Vasco DW, Myer L. 2010. Coupled reservoir geomechanical analysis of CO2 injection and ground deformations at In Salah, Algeria. International Journal of Greenhouse Gas Control, 4:225–230. https://doi.org/10.1016/j.ijggc.2009.10.017.

Vilarrasa V, Bolster D, Olivella S, Carrera J. 2010. Coupled hydromechanical modeling of CO2 sequestration in deep saline aquifers. International Journal of Greenhouse Gas Control, 4:910–919. https://doi.org/10.1016/j.ijggc.2010.06.006.

Vilarrasa V, Olivella S, Carrera J. 2011. Geomechanical stability of the caprock during CO2 sequestration in deep saline aquifers. Energy Procedia, 4:5306–5313. https://doi.org/10.1016/j.egypro.2011.02.511.

Wang JG, Wang H. 2018. Sealing efficiency analysis for shallow-layer caprocks in CO2 geological storage. Environmental Earth Sciences, 77:738. https://doi.org/10.1007/s12665-018-7924-2.

Wang J G, Ju Y, Gao F, et al. 2015. Effect of CO2 sorption-induced anisotropic swelling on caprock sealing efficiency. Journal of Cleaner Production, 103:685–695. https://doi.org/10.1016/j.jclepro.2014.08.024.

Wang JG, Peng Y. 2014. Numerical modeling for the combined effects of two-phase flow, deformation, gas diffusion and CO2 sorption on caprock sealing efficiency. Journal of Geochemical Exploration, 144:154–167. https://doi.org/10.1016/j.gexplo.2013.12.011.

Xia L, Yvonnet J, Ghabezloo S. 2017. Phase field modeling of hydraulic fracturing with interfacial damage in highly heterogeneous fluid-saturated porous media. Engineering Fracture Mechanics, 186:158–180. https://doi.org/10.1016/j.engfracmech.2017.10.005.

Yamamoto S, Miyoshi S, Sato S, et al. 2013. Study on geomechanical stability of the aquifer-caprock system during CO2 sequestration by coupled hydromechanical modelling. Energy Procedia, 37:3989–3996. https://doi.org/10.1016/j.egypro.2013.06.298.

Zeng Q, Bo L, Liu W, et al. 2023. An investigation of hydraulic fracture propagation in multi-layered formation via the phase field method. Computers and Geotechnics, 156:105258. https://doi.org/10.1016/j.compgeo.2023.105258.

Zhou S, Zhuang X, Rabczuk T. 2018. A phasefield modeling approach of fracture propagation in poroelastic media. Engineering Geology, 240:189–203. https://doi.org/10.1016/j.enggeo.2018.04.008.

Zhou S, Rabczuk T, Zhuang X. 2018. Phase field modeling of quasi-static and dynamic crack propagation: COMSOL implementation and case studies. Advances in Engineering Software, 122:31–49. https://doi.org/10.1016/j.advengsoft.2018.03.012.

Zhou S, Zhuang X, Rabczuk T. 2020. Phase field method for quasi-static hydro-fracture in porous media under stress boundary condition considering the effect of initial stress field. Theoretical and Applied Fracture Mechanics, 107:102523. https://doi.org/10.1016/j.tafmec.2020.102523.

Zhuang X, Zhou S, Sheng M, et al. 2020. On the hydraulic fracturing in naturally-layered porous media using the phase field method. Engineering Geology, 266:105306. https://doi.org/10.1016/j.enggeo.2019.105306.

Zhang X, Lu Y, Tang J, et al. 2017. Experimental study on fracture initiation and propagation in shale using supercritical carbon dioxide fracturing. Fuel, 190:370–378. https://doi.org/10.1016/j.fuel.2016.10.120.

IPCC. 2007. Climate Change 2007: Mitigation of Climate Change. Contribution of Working Group III to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change.

IPCC. 2014. Climate Change 2014: Mitigation of Climate Change. Contribution of Working Group III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change.

Downloads

Download data is not yet available.

Downloads

Published

2026-01-21

How to Cite

Fu, Y., Qiao, S., Wang, H., Liu, J., Li, Z., & Sheng, J. (2026). Investigating fracture activation and CO2 migration in layered shale caprock: a phase-field approach. GeoStorage, 2(1), 27–39. https://doi.org/10.46690/gs.2026.01.03

Issue

Section

Articles